A solar cell, or photovoltaic cell, is a device that converts light into electric current using the photovoltaic effect. The first solar cell was constructed by Charles Fritts in the 1880s.[11] The German industrialist Ernst Werner von Siemens was among those who recognized the importance of this discovery.[12] In 1931, the German engineer Bruno Lange developed a photo cell using silver selenide in place of copper oxide,[13] although the prototype selenium cells converted less than 1% of incident light into electricity. Following the work of Russell Ohl in the 1940s, researchers Gerald Pearson, Calvin Fuller and Daryl Chapin created the silicon solar cell in 1954.[14] These early solar cells cost US$286/watt and reached efficiencies of 4.5–6%.In 1957, Mohamed M. Atalla developed the process of silicon surface passivation by thermal oxidation at Bell Labs.[16][17] The surface passivation process has since been critical to solar cell efficiency.[18]
As of 2022 over 90% of the market is crystalline silicon. The array of a photovoltaic system, or PV system, produces direct current (DC) power which fluctuates with the sunlight's intensity. For practical use this usually requires conversion to alternating current (AC), through the use of inverters.[10] Multiple solar cells are connected inside panels. Panels are wired together to form arrays, then tied to an inverter, which produces power at the desired voltage, and for AC, the desired frequency/phase.
Many residential PV systems are connected to the grid wherever available, especially in developed countries with large markets.[20] In these grid-connected PV systems, use of energy storage is optional. In certain applications such as satellites, lighthouses, or in developing countries, batteries or additional power generators are often added as back-ups. Such stand-alone power systems permit operations at night and at other times of limited sunlight.